By Carsten Bolm, F. Ekkehardt Hahn
Using secondary interactions for the activation of non-reactive substrates constitutes a brand new and smooth strategy in catalysis.
this primary complete therapy of this significant examine box covers the complete box and divulges the hyperlinks among many of the chemical disciplines. It therefore adopts an interdisciplinary procedure, making it of curiosity to the entire chemical community.
A needs to for natural, inorganic, catalytic and complicated chemists, in addition to these operating with/on organometallics.Content:
Chapter 1 Chemistry of Metalated box Molecules (pages 1–15): Berthold Kersting
Chapter 2 The Chemistry of Superbasic Guanidines (pages 17–37): Jorg Sundermeyer, Volker Raab, Ekatarina Gaoutchenova, Udo Garrelts, Nuri Abacilar and Klaus Harms
Chapter three Iron Complexes and Dioxygen Activation (pages 39–51): Thomas Nebe, Jing?Yuan Xu and Siegfried Schindler
Chapter four Tuning of constructions and homes of Bispidine Complexes (pages 53–63): Peter Comba and Marion Kerscher
Chapter five Novel Phosphorus and Nitrogen Donor Ligands Bearing Secondary Functionalities for functions in Homogeneous Catalysis (pages 65–88): Anna?Katharina Pleier, Yu solar, Anett Schubert, Dirk Zabel, Claudia may perhaps, Andreas Reis, Gotthelf Wolmershauser and Werner R. Thiel
Chapter 6 Square?Pyramidal Coordinated Phosphine Iron Fragments: A story of the unforeseen (pages 89–102): Andreas Grohmann and Stephan Kohl
Chapter 7 Regioselective Catalytic job of Complexes with NH, NR?Substituted Heterocyclic Carbene Ligands (pages 103–122): Siegfried R. Waldvogel, Anke Spurg and Prof. Dr. F. Ekkehardt Hahn
Chapter eight Functionalized Cycloheptatrienyl?Cyclopentadienyl Sandwich Complexes as construction Blocks in Metallo?Supramolecular Chemistry (pages 123–146): Matthias Tamm
Chapter nine Monosaccharide Ligands in Organotitanium and Organozirconium Chemistry (pages 147–164): Peter Kitaev, Daniela Zeysing and Jurgen Heck
Chapter 10 Reactions of C?F Bonds with Titanocene and Zirconocene: From Secondary interplay through Bond Cleavage to Catalysis (pages 165–182): Uwe Rosenthal, Vladimir V. Burlakov, Perdita Arndt, Anke Spannenberg, Ulrike Jager?Fiedler, Marcus Klahn and Marko Hapke
Chapter eleven Bisazines within the Coordination Sphere of Early Transition Metals (pages 183–207): Ruediger Beckhaus
Chapter 12 Bifunctional Molecular platforms with Pendant Bis(pentafluorophenyl)boryl teams: From Intramolecular CH?Activation to Heterolytic Dihydrogen Splitting (pages 209–230): Michael Hill, Christoph Herrmann, Patrick Spies, Gerald Kehr, Klaus Bergander, Roland Frohlich and Gerhard Erker
Chapter thirteen Ruthenium?Containing Polyoxotungstates: constitution and Redox task (pages 231–243): Ulrich Kortz
Chapter 14 From NO to Peroxide Activation by means of version Iron(III) Complexes (pages 245–272): Alicja Franke, Natalya Hessenauer?Ilicheva, Joo?Eun Jee and Rudi van Eldik
Chapter 15 artificial Nitrogen Fixation with Molybdenum and Tungsten Phosphine Complexes: New advancements (pages 273–296): Gerald Stephan and Felix Tuczek
Chapter sixteen Directed C?H Functionalizations (pages 297–312): Prof. Dr. Carsten Bolm
Chapter 17 improvement of Novel Ruthenium and Iron Catalysts for Epoxidation with Hydrogen Peroxide (pages 313–337): guy family Tse, Bianca Bitterlich and Matthias Beller
Chapter 18 Pentacoordinating Bis(oxazoline) Ligands with Secondary Binding websites (pages 339–348): Caroline A. Schall, Michael Seitz, Anja Kaiser and Oliver Reiser
Chapter 19 Flavin Photocatalysts with Substrate Binding websites (pages 349–358): Harald Schmaderer, Jiri Svoboda and Burkhard Konig
Chapter 20 New Catalytic Cu?, Pd? and Stoichiometric Mg?, Zn?Mediated Bond Activations (pages 359–377): Tobias Thaler, Hongjun Ren, Nina Gommermann, Giuliano C. Clososki, Christoph J. Rohbogner, Stefan H. Wunderlich and Paul Knochel
Chapter 21 From Cobalt(II)?Activated Molecular Oxygen to Hydroxymethyl?Substituted Tetrahydrofurans (pages 379–396): Barbara Menendez Perez, Dominik Schuch and Jens Hartung
Chapter 22 Regiodivergent Epoxide commencing (pages 397–409): Andreas Gansauer, Florian Keller, Chun?An Fan and Peter Karbaum
Chapter 23 Supramolecular packing containers: Host?Guest Chemistry and Reactivity (pages 411–425): Markus Albrecht
Chapter 24 Self?Assembly of Dinuclear Helical Metallosupramolecular Coordination Compounds (pages 427–446): Ulf Kiehne, Jens Bunzen and Arne Lutzen
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Extra resources for Activating Unreactive Substrates: The Role of Secondary Interactions
M. (1994) Container Molecules and their Guests, Royal Society of Chemistry, Cambridge. N. and Verboom, W. (2007) Angewandte Chemie – International Edition, 46, 2366–2393. 3 Rissanen, K. (2005) Angewandte Chemie – International Edition, 44, 3652–3654. 4 Hecht, S. J. (2001) Angewandte Chemie – International Edition, 40, 74–91. , Martin, T. , Jr (1998) Science, 279, 1021–1023. , Sadowski, O. and Tepper, E. (2003) Angewandte Chemie – International Edition, 42, 3171–3173. -L. J. and Brown, N. (2002) Angewandte Chemie – International Edition, 41, 96–99.
Tertiary amine TMEDA did not yield any product . 1) and 14% isolated yield for the aliphatic bis-guanidine [Cu(TMGEn)I] (TMGEn ¼ 1,2-tetramethylguanidinoethane). 3 Some Perspectives in Proton Sponge Chemistry and in particular the proton sponge TMGN, are promising catalyst ligands. Further studies with NH-functional guanidines are ongoing. It is important to note that the performance of this catalytic reaction strongly depends on the quality and commercial source of the heterogeneous inorganic base K3PO4.
The metal-mediated combination of superoxide and NO is considered to play a role in nitric oxide biochemistry. 7). It was demonstrated by ESI mass spectroscopy that copper-mediated coupling of isotopically labeled superoxo ligands with NO leads to the formation of [(TMG3tren)Cu(m1 -16 O-16 O-NO)] B(C6F5)4 and [(TMG3tren)Cu(h1 -18 O-18 O-NO)] B(C6F5)4 . The borate anion allows monitoring of this reaction in solution at low temperature. DFT calculations support the h1 coordination mode of the peroxonitrite ion.